Why is extraction the bottleneck in green ammonia, not synthesis?
Because synthesis has been solved and extraction has not. Renewable electricity, electrolysis and Haber-Bosch synthesis all work at modular scale today. Separating the ammonia back out of the synthesis loop is the step that still relies on hundred-year-old physics, and at small scale it is where the economics break.
In a decentralised plant, the extraction step alone can absorb up to a quarter of total capital cost and more than 20% of operating cost. That is usually enough to stop a project reaching a final investment decision.